Product ID:FREE-LON AEROSOL (0301)
MSDS Date:06/15/1988
FSC:6850
NIIN:00N011540
MSDS Number: BJFHM

SELIG CHEMICAL INDUSTRIES

840 SELIG DRIVE SW
ATLANTA, GA 30378
US

Emergency Phone: 404-691-9220;800-424-9300 CHEMTREC

Info Phone: 404-691-9220

Cage: 86938

SELIG CHEMICAL INDUS, DIV OF NATIONAL SERVICE INDUS

ATLANTA, GA 30378 US

Telephone: 404-691-9220

Cage: 86938

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 40%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 10 - 20%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HYDROCARBON PROPELLANT

Fraction By Weight: 40-50%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Explanation of Carcinogenicity:METHYLENE CHLORIDE:INAD EVID FOR CARC IN
HUMANS;SUFF EVID FOR CARC IN ANIMALS (IARC,1987).ACGIH A2=SUSP
HUMAN (SEE SUPP)
Effects of Overexposure:EYES:CAN BE IRRITATING UPON CONTACT.SKIN:CAN
DEFAT SKIN.INGESTION:HARMFUL IF SWALLOWED.CAN CAUSE NAUSEA AND
VOMITING.INHALATION:CAN CAUSE DIZZINESS,NAUSEA AND HEADACHE.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMED W/ PLENTY OF WATER FOR AT LEAST 15
MIN.CONSULT MD.SKIN:WASH W/ SOAP & WATER.USE SKIN CREAM W/
LANOLIN.INGEST:GIVE PLENTY OF WATER.DO NOT INDUCE VOMIT.SEEK MED
ATTN IMMED.INH:MOVE TO F RESH AIR.GIVE O*2,IF NEEDED.SEE MD.MD
NOTE:1,1,1-TRICHLOROETHANE & METHYLENE CHLORIDE HAVE BEEN SHOWN
TO/ARE SUSP OF SENSITIZING THE MYOCARDIUM TO
EPINEPHRINE.EPINEPHRINE/ITS CONGENERS COULD (SEE SUP)

Flash Point:0F,-18C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:DRY CHEMICAL
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA & FULL PROTECTIVE
EQUIPMENT ABOVE 500F,260C.
Unusual Fire/Explosion Hazard:WHEN AEROSOLS ARE EXPOSED TO TEMP ABOVE
120F,49C CANS MAY BURST.HAZARDOUS DECOMPOSITION
PRODUCTS:PHOSGENE,CHLORINE,HCL AND CO.

Spill Release Procedures:LARGE SPILLS ARE UNLIKELY DUE TO AEROSOL
PACKAGING.IF SPILLED,ABSORB WITH AN ABSORBENT MATERIAL;PICK UP AND
DEPOSIT IN SEALABLE CONTAINER FOR DISPOSAL AS HAZ WASTE.THOROUGHLY
CLEAN SPILL AREA W/ DETER GENT SOLUTION.RINSE THOROUGHLY W/
CLEANWATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.HARMFUL
IF SWALLOWED.AVOID CONTACT W/ SKIN & EYES.CONTR MAY BURST IF HEATED
ABOVE 120F,49C.AVOID PRLNG EXPOS TO VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT MAY CAUSE
THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:CHEMICAL CARTRIDGE RESPIRATOR IF IN CONFINED
AREA.
Ventilation:MECHANICAL VENTILATION
Protective Gloves:RUBBER OR NEOPRENE.
Eye Protection:NOT REQ UNLESS SPLASHING CONDITIONS.
Other Protective Equipment:N/K
Work Hygienic Practices:N/K
Supplemental Safety and Health
VP:46 PSIG @ 75F,24C.FL PT METH:CSMA FLAME EXT METHOD.TLV:470 PPM
(MFR).ENTRY RTE:INHAL/SKIN/INGEST .EXPLAN OF CARC:CARCIN
(1990).SUSP HUMAN CARC/KNOWN ANIMAL CARCIN (NTP,1989).KNOWN TO
CAUSE CA NCER (CAL PROP 65,1988).WASTE DISP METH:313:LISTED.FIRST
AID PROC:PRECIP A FATAL ARRHY IN PERSONS EXPOSED TO THESE CHEM.

Boiling Pt:B.P. Text:142F,61C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Spec Gravity:1.335 (WATER=1)
Evaporation Rate & Reference:>1 (IPA=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MILKY,WHITE LIQUID WITH A MILD SWEETISH ODOR.
Percent Volatiles by Volume:98

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD
PHOSGENE,CHLORINE,HCL AND CO.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISP MUST BE IAW FED,STATE,LOCAL REGS .PROD
CONSUMED IN USE.DO NOT CRUSH,PUNCTURE,INCIN SPENT CONTR.SML HAZ
WASTE GENERATORS CONSULT CFR TITLE 40,PART 261.5 FOR POSS
EXEMPTIONS.1,1,1-TRICHLOROET HANE & METHYLENE CHLORIDE:SARA TITLE
III (SEE SUP)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.